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Scientists decipher key principle behind reaction of metalloenzymes

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What enables electrons to be transferred swiftly, for example during photosynthesis? An interdisciplinary team of researchers has worked out the details of how important bioinorganic electron transfer systems operate. Using a combination of very different, time-resolved measurement methods at DESY's X-ray source PETRA III and other facilities, the scientists were able to show that so-called pre-distorted states can speed up photochemical reactions or make them possible in the first place. The group headed by Sonja Herres-Pawlis from the RWTH Aachen University Michael Rübhausen from the University of Hamburg and Wolfgang Zinth from Munich's Ludwig Maximilian University, is presenting its findings in the journal Nature Chemistry.

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